The influence of ion pairing on the electroreduction of nitromesitylene in aprotic solvents. 1. Thermodynamic aspects
β Scribed by Chauhan, B. G.; Fawcett, W. R.; Lasia, A.
- Book ID
- 121251237
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 824 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
The qualitative effects of ion pairing have been discussed with respect to electrode reactions for which double layer effects are important ~. In the case of reduction reactions, three effects have been considered, namely, ion pairing between a reacting anion and cations in the bulk of the solution
In the rather polar organic solvents dimethoxyethane, tetrahydrofuran and 3-methyltetrahydrofuran, the behaviour of contact ion pairs, solvent-separated ion pairs and free carbanions of polystyryl sodium has been investigated by kinetic and conductivity measurementsβ’ Both the equilibrium between the