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The influence of iodoacetate on the mechanism of nuclear glucose oxidation

โœ Scribed by A. W. T. Konings

Book ID
112699139
Publisher
Springer
Year
1971
Tongue
English
Weight
269 KB
Volume
27
Category
Article
ISSN
1420-682X

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The mechanism of the formation of lactones by free radical additions of tri-nbutyltin iodoacetate to alkenes occurs through a two-step process: a homolytic addition of the ester (addition of 'CH2-C02SnBu3, iodine transfer), followed by a fast ionic cyclization with elimination of tri-n-butyltin iodi