The influence of intramolecular charge redistribution at the photoexcitation stage on the rate of subsequent electron transfer
β Scribed by S. S. Khokhlova; V. A. Mikhailova; A. I. Ivanov
- Book ID
- 111472279
- Publisher
- Pleiades Publishing
- Year
- 2007
- Tongue
- English
- Weight
- 248 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1990-7931
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π SIMILAR VOLUMES
An unusually strong temperature dependence on the intramolecular eiectron-transfer rate has been observed for bridged donor-acceptor compounds in propylene glycol solution. In the frame of recent electron-transfer theories this effect reflects the influence of dielectric relaxation dynamics on elect
The present work rests on non-adiabatic electron transfer theory. The influence of the molecular dynamics (MD) of exchanging groups on the electron transfer rate is treated. The MD of exchanging groups is described as a stochastic process with two possible states. The transfer between these two stat