𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The influence of hyperconjugation on properties of borane adducts

✍ Scribed by Keith F. Purcell; R. L. Martin

Publisher
Springer
Year
1974
Tongue
English
Weight
537 KB
Volume
35
Category
Article
ISSN
1432-2234

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The 1,1,3,3-Tetramethylguanidine–Borane
The 1,1,3,3-Tetramethylguanidine–Borane Adduct: Theoretical Comparison of the Bonding Properties in Amine– and Guanidine–Borane Adducts
✍ Oxana Ciobanu; Simone Leingang; Hubert Wadepohl; Hans-Jörg Himmel 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB

## Abstract Herein we report on the synthesis and characterization of the adduct 1,1,3,3‐tetramethylguanidine–borane, H~3~B·N(H)C(NMe~2~)~2~, and a general inspection of the bonding properties of guanidine adducts to BH~3~. The new compound was characterized by its vibrational, NMR and mass spectra

Palladium catalyzed activation of borane
Palladium catalyzed activation of borane–amine adducts: rate enhancement of amine–borane methanolysis in the reduction of nitrobenzenes to anilines
✍ Michel Couturier; John L Tucker; Brian M Andresen; Pascal Dubé; Steven J Brenek; 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 71 KB

Hydrolytically stable borane-amines can be activated in situ through palladium catalysis and perform reductions not possible otherwise. Hence, borane-trimethylamine is an efficient hydrogen-transfer reagent for the open vessel reduction of nitroaryls to anilines. Likewise, the palladium catalyzed me

Influence of the metabolic properties of
Influence of the metabolic properties of human cells on the kinetic of formation of the major benzo[a]pyrene DNA adducts
✍ Caroline Marie; Anne Maître; Thierry Douki; Mathilde Gateau; Adeline Tarantini; 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 418 KB 👁 1 views

## Abstract Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental contaminants. Some of them, including benzo[a]pyrene (B[a]P), are tumorigenic due to their ability to generate DNA adducts. In order to define potential biomarkers of B[a]P exposure, the aim of the study was to identif