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The influence of errors of Arrhenius parameter calculation on the exactness of the solution of the direct kinetic problem

✍ Scribed by S.V. Vyazovkin; A.I. Lesnikovich


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
855 KB
Volume
182
Category
Article
ISSN
0040-6031

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A detailed statistical study is presented, based on simulated experimental data, on the estimation of activation parameters using the Arrhenius equation: k = A exp!B/T). The close correlation of the two parameters is shown, which requires the computation of the covariance matrix for the representat