The influence of diffusion on the rate of a reversible quasi-unimolecular reaction in one, two or three dimensions
β Scribed by Nancy L. Thompson; Thomas P. Burghardt
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 845 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0301-4622
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π SIMILAR VOLUMES
The particle number N fluctuates in a spherical volume fragment of a uniform electron gas. In an ideal classical-gas or "Hartree" model, the fluctuation is strong, with ( N ) 2 = N . We show in detail how this fluctuation is reduced by exchange in the ideal Fermi gas and further reduced by Coulomb c
Usmg the blvanate Laplace transform method, the density functions of the residence time dlstnbutlon of the product and reactant, respectively, are determmed m terms of the four roots of the charactenstlc equation and asymptotic relations for the mean and vanance of these dlstnbutlons are given In th