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The influence of cyclodextrin complexation on proton transfer in piperidinomethyl-2-naphthol

✍ Scribed by G. Köhler; H. Martinek; W. Parasuk; K. Rechthaler; P. Wolschann


Publisher
Springer Vienna
Year
1995
Tongue
English
Weight
166 KB
Volume
126
Category
Article
ISSN
0026-9247

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📜 SIMILAR VOLUMES


On the mechanism of proton transfer in t
✍ Martin J. Scanlan; Ian H. Hillier 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 234 KB

The saddle point for the proton transfer invohred in the equilibrium 2-hydroxypyridine = 2-pyridone has been calculated in it 3-21G basis to be 206 kJ mol-\* above the hctim form, for a unimo!ecular mechanism. This barrier is estimated to be rc-du=d to 46 kJ mol-l in the self-associated dimer.