There has been determination of the molecular weight distributions which are to be expected when symmetrical multifunctional initiators of the structure
The influence of chain initiation rate on molecular weight dispersion in free radical polymerizations
β Scribed by Tadmor, Zehev ;Biesenberger, Joseph A.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1965
- Tongue
- English
- Weight
- 231 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0449-2986
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π SIMILAR VOLUMES
Free-radical polymerization of styrene was carried out in the presence of chain transfer agents (CTAs) with functionality, f Ο 1-4. The size exclusion chromatography (SEC) with an ultraviolet absorption detector (UV) was used to measure the molecular weight distribution (MWD). A Monte Carlo simulati
## Abstract The propagation rate coefficient __k__~p~ was determined for hydroxypropyl methacrylate by applying pulsed laser initiated polymerizations and subsequent analysis of the polymer by sizeβexclusion chromatography. __k__~p~ data were derived for polymerizations in bulk and in several solve