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The influence of an intramolecular relaxation process on the frequency-time behaviour or the fluorescence of tetraphenylethylene in highly viscous solutions

✍ Scribed by H.H Klingenberg; E Lippert; W Rapp


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
265 KB
Volume
18
Category
Article
ISSN
0009-2614

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✦ Synopsis


Within a certain viscosity range the fluorescence decay time of tetraphenylcthylcne was found to va@ considerably with respect to the selected emission wavenumber interval. This anomalous behaviour is explained by an intramolecular conformation change of the excited state during emission.