✦ LIBER ✦

The influence of an electric field on adsorption of organic substances at electrodes—I. Generalization of the Frumkin's theory from the modified model of two parallel condensers

✍ Scribed by D. Schuhmann

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 698 KB
Volume: 32
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(87)85063-6

No coin nor oath required. For personal study only.

✦ Synopsis

The modified model of two parallel condensers [D. Schuhmann, J. electroonol. Gem. 201, 247 (1986)] based on a new demonstration of the Helmholtz formula provides a consistent electrostatic interpretation of the influence of an electric field on adsorption of organic substances. Following the procedure proposed by the soviet school, deviations, with respect to congruence, due to variations in coverage of the inner properties of the surface layers, are treated for some molecular examples in the frame of the modified model.

📜 SIMILAR VOLUMES

Comments on the paper “the influence of

Comments on the paper “the influence of an electric field on adsorption of organic substances—II. Application of the modified model of two parallel condensers to ethylene glycol solutions”

✍ S. Trasatti 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 143 KB

The correlations on which the conclusions of the paper under discussion rest are shown to lack internal consistency. Calculations of molecular dipoles from thermodynamic adsorption data are pointed out to be physically ambiguous