The importance of ground-state vibronic mixing in molecular Raman scattering

✍ Scribed by Benjamin Scharf; Yehuda B. Band

• Publisher: Elsevier Science
• Year: 1982
• Tongue: English
• Weight: 481 KB
• Volume: 91
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(82)83305-8

✦ Synopsis

We consldcr Albrccht's theory for Raman snttcring of fundamentals m tbc far and prc-resor~nn? rcglons DcstrucWc mlerfcrcnces inhcrcnt to thcd and B terms augment the convcntlonally supprcsscd C lcrm dramatrcally. Raman c~ta~on profiles for the YI (a~~) and v~(c$ fundamcnlals m bcrucnc can bc well fitted wrrh thcorctrcal C-term prordcs mvolvmg the 'El&-n*) s1ate at 1800 A.