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The importance of alkene and alkyne structure on their relative rates of bromination

โœ Scribed by Schmid, G. H.; Modro, A.; Yates, K.

Book ID
127074437
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
376 KB
Volume
42
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

The relative rates of electron-rich and
The relative rates of electron-rich and electron-deficient alkene cycloadditions to benzyne. Enhanced electrophilicity as a consequence of alkyne bending distortions.
โœ Nelson G. Rondan; L.N. Domelsmith; K.N. Houk; A.T. Bowne; R.H. Levin ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 255 KB

Benzyne reacts more rapidly with electron-rich alkenes than electron-deficient alkenes, a result of the abnormally low energy LUMO of benzyne, which results from the acetylene bending enforced by the benzyne geometry.