The conditions that favor the formation of nitrous oxide from char under fluidized bed combustion conditions are shown to be the oxidation of the char to make the nitrogen bound in the heterocyclic rings accessible so that it can react heterogeneously either with oxygen to form NO or with nitric oxi
The identification of unusual microscopic features in coal and their derived chars: Influence on coal fluidized bed combustion
β Scribed by B. Valentim; M.J. Lemos de Sousa; P. Abelha; D. Boavida; I. Gulyurtlu
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 651 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0166-5162
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β¦ Synopsis
During the petrographic study of seven feed coals from different origins, it was found that these coals presented microfeatures such as: material size, shape, weathering, thermally affected particles and contamination. After devolatilization under fluidized bed conditions, some chars presented the consequences of the above mentioned microfeatures, i.e., unreacted coal, unswelled particles, coatings and microstratification.
Since the amounts of the microfeatures observed were low (less than 1%), the present study is essentially observational/ descriptional. However, it seems very likely, from the observations that were made, that the occurrence of one or more of these microfeatures in coal, depending on their kind and abundance, may have significant effect on the coal devolatilization.
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