✦ LIBER ✦
The identification of an electronic Raman transition for the hexa-aquavanadium(III) ion. A direct spectroscopic determination of the trigonal field splitting of the 3T1g ground term
✍ Scribed by Stephen P. Best; Robin J.H. Clark
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 422 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
An elecrronic Raman rransiGon (3E, c3As) has been observed between the nigonally split componems or Ihe 3T,,(F) ground lerm of the hexa-aquavanadium(II1) ion in CsV(SO,),-lZH,O and NH,V(S0,)I.12H20. The magnitude or Ihe spliuing (1940 cm-') is in agreemem with that estimated from earlier magnelic measuremenls (= 2000 cm-'). The appearance of sh-ucwre on the eleckonic Raman band can be interpreted in ~crrns or transikns bewxen spin-orbit coupled slales.