The Hydrolysis of Some Quinone Oximes
β Scribed by Sumerford, W. T.; Dalton, D. N.
- Book ID
- 118165937
- Publisher
- American Chemical Society
- Year
- 1944
- Tongue
- English
- Weight
- 256 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The conversion of 17a-acetoxy-6a-methyl-4-pregnen-3,20-dione 3-oxime to the corresponding diketone in acidic media was found to be a first-order reaction at 37". The effects of incorporating ester groupings at the oxime function or a t the C-17 position and modifications in ring B were also investig
The intermediacy of the quinone methide 1 in the photochemical transformations of spirodienone 2 was deduced on the basis of formation of the ether-incorporated product 3\* (2,3) This postulate was strengthened as a result of experiments with spirodienone 1 labeled with deuterium on the cyclopropane