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The Hydrolysis of Optically Active Secondary Butyl Hydrogen Sulfate 1

✍ Scribed by Burwell, Robert L.


Book ID
127334732
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
660 KB
Volume
74
Category
Article
ISSN
0002-7863

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A new optically active secondary diphosp
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S,S)-1,2-Bis(boranato(tert-butyl)phosphino)ethane has been synthesized efficiently and in excellent enantioselectivity. This secondary diphosphine serves as the starting material for an elegant preparation of (R,R)-1,2-bis(boranato(tertbutyl)methylphosphino)ethane, known as (R,R)-t-Bu-BisP\*-borane.