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The hydrogenation of alkadienes: VIII. Deuterium tracer study of alkane formation in the palladium-catalyzed hydrogenation of propadiene and of 1,2-butadiene and its implications concerning the breakdown of selectivity in ethyne hydrogenation

✍ Scribed by Roger G. Oliver; Peter B. Wells

Book ID
113175623
Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
524 KB
Volume
47
Category
Article
ISSN
0021-9517

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✍ Françoise Hénin; Stéphane Létinois; Jacques Muzart 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 218 KB

At room temperature, the presence of hydrogen and catalytic amounts of Pd/C induced the formation of 1,3-oxazolidines from nitriles and 1,2-amino alcohols. The subsequent reductive cleavage of the NC-O bond of lhese heterocycles occurred under the same conditions. Thus, this methodology provides a n