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The Homogeneous Unimolecular Decomposition of Gaseous Alkyl Nitrites. IV. The Decomposition of Iso-propyl Nitrite

โœ Scribed by Steacie, E. W. R.; Shaw, G. T.


Book ID
120134084
Publisher
The Royal Society
Year
1935
Tongue
English
Weight
484 KB
Volume
151
Category
Article
ISSN
0962-8444

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The mechanism for unimolecular fragmentation of the methyl nitrite radical cation, CH,ONO+, has been determined by mass spectrometric techniques applying deuterium and I80 labelling. It could be unambiguously concluded that methyl nitrite radical cations possessing low internal energy fragment exclu