𝔖 Bobbio Scriptorium
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The Hindered Rotation in Various Fields of Cubic Symmetry

✍ Scribed by H. U. Beyeler


Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
367 KB
Volume
52
Category
Article
ISSN
0370-1972

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✦ Synopsis


Abstract

The hindered rotation in cubic fields of various shapes and intensities is studied. The β€œDevonshire Model” is extended to include cubic fields being linear combinations of spherical harmonics of order four and six. In contrast to Devonshire's potential, this two parameter manifold of potentials contains some with the energy minima at the γ€ˆ110〉 directions. Agreement is found between the low‐lying rotator levels in a large hindering potential and these of harmonic oscillators localized in the minimum wells of the potential.


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Hindered rotation of the ammonium ion in
✍ David Smith πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 English βš– 350 KB

The hindered rohtiond energy Ievels of the ammonium ion in (NH4)zSnCl6 have been computed\_ These energy levels uad CO interpret the Iibrstionat frequencies, tunneliq frequencies, and rotational heat capacity of the ammonium ion