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The High-Valent Compound of Cytochrome P450: The Nature of the Fe−S Bond and the Role of the Thiolate Ligand as an Internal Electron Donor

✍ Scribed by François Ogliaro; Shimrit Cohen; Michael Filatov; Nathan Harris; Sason Shaik

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
44 KB
Volume
113
Category
Article
ISSN
0044-8249

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The High-Valent Compound of Cytochrome P
The High-Valent Compound of Cytochrome P450: The Nature of the Fe−S Bond and the Role of the Thiolate Ligand as an Internal Electron Donor
✍ François Ogliaro; Shimrit Cohen; Michael Filatov; Nathan Harris; Sason Shaik 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB

Recently, Schlichting et al. [1] have used time-lapse X-ray crystallography to ªphotographº the hydroxylation pathway of camphor by cytochrome P450 cam , which includes the elusive, high-valent iron-oxene species (1 in Scheme 1 a). In response to this exciting work, we present here an extensive dens