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The high-temperature pyrolysis of formaldehyde: kinetics and energy disposal to CO(v)

✍ Scribed by J.P. Buxton; C.J.S.M. Simpson

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
780 KB
Volume
128
Category
Article
ISSN
0009-2614

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✦ Synopsis

The kinetics of the pyrolysis of formaldehyde have been followed behind the incident shock wave using a cw CO laser. Both CO production and H2C0 decay have been monitored by direct laser gain. Observed rate constants are in excellent agreement with the results of Dean, Craig, Johnson, Schultz and Wang over the temperature range 1750-2220 K. We have measured the nascent vibrational distribution of the CO product at 2300 Q T< 2400 K. The nascent vibrational distribution of the CO is found to be colder than the equilibrium Boltzmann distribution.

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