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The HfCl4-Mediated Diels—Alder Reaction of Furan.

✍ Scribed by Yujiro Hayashi; Masahiko Nakamura; Shigehiro Nakao; Tae Inoue; Mitsuru Shoji

Publisher
John Wiley and Sons
Year
2003
Weight
222 KB
Volume
34
Category
Article
ISSN
0931-7597

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The simple chemical modification by Diels ± Alder reactions of the cyclic hexamer of furan and acetone, utilising two readily accessible dienophiles, benzyne and dimethylacetylenedicarboxylate (DMAD), is described. The studies have explored the ease with which different furan units within the macroc