✦ LIBER ✦
The hex-5-enose degradation: Cleavage of modified glycosiduronic acid linkages in methylated Khaya ivorensis gum
✍ Scribed by Gerald O. Aspinall; Lev Khondo; John A. Kinnear
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 757 KB
- Volume
- 179
- Category
- Article
- ISSN
- 0008-6215
No coin nor oath required. For personal study only.
✦ Synopsis
Scheme 1. Transformations of uranic acid residues leading to the generation of 6-deoxy+iodohexose residues in methylated glycan: (i) methylation, CH,I/kCH,SOCH,;
(ii) reduction. LiAID,; (iii) reduction, "superhydride";
(iv) trideuteri omethylation.
CD,I/~CH$OCH,; (v) iodination, NISIPPh,.