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The HeI PE spectrum and electronic structure of nitroethene

✍ Scribed by Ljiljana Paša-Tolić; Leo Klasinc; Sean P. McGlynn

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
280 KB
Volume
170
Category
Article
ISSN
0009-2614

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✦ Synopsis

The He1 photoelectron (PE) spectrum of nitroethene is presented. Four groups of bands are observed, the group ranges being 11-12.5, 14-15.5, 16-17 and 17-18 eV. Pine structure analysis of the first group (assigned empirically as a$, ttccn n$ and t$, with the specific order of the last two being uncertain) indicates that the electrons of the NO, group are distributed much the same in both nitromethane and nitroethene. A comparison with quantum chemical results is given.

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