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The Heat of Formation of Cyclobutadiene

โœ Scribed by Alireza Fattahi; Lev Lis; Zhixin Tian; Steven R. Kass


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
108 KB
Volume
118
Category
Article
ISSN
0044-8249

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Over the past several years, a controversy has developed over the value of the heat of formation of the vinyl radical. Reported values for AHf(C2H3) range from 59.6 kcal/mol [l] to 71.5 kcal/mol [2] and even higher values can be cited from earlier work. Recently, Ayranci and Back [31 reported a valu

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An examination of the results of measurements of the forward and reverse rate constants for the reaction shows that agreement between the kinetics and the thermochemistry is achieved only through use of a value of AH,-(C,H5) = 28 kcal mol-'. This system therefore provides further support ?or the re