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The halogen-nitrile exchange reaction as a route to pyrimidinecarbonitriles

โœ Scribed by Thomas J. Schwan; Howard Tieckelmann

Book ID
112121233
Publisher
Journal of Heterocyclic Chemistry
Year
1964
Tongue
English
Weight
173 KB
Volume
1
Category
Article
ISSN
0022-152X

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## Photochemical reactions of the vinyloxyketones (3) give a regioselective intramolecular cycloaddition to afford oxetanes (4); the latter react stereospecifically with methanol to yield medium-ring acetals (51.