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The halocarbon contamination problem. Part I: Atmospheric effects of halocarbons

✍ Scribed by B.A. Thrush

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
409 KB
Volume
2
Category
Article
ISSN
0140-7007

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πŸ“œ SIMILAR VOLUMES

Substituent effects on the disproportion
Substituent effects on the disproportionation-combination rate constant ratios for gas-phase halocarbon radicals. Part III: Reactions of CF3 + CF3CH2 CHCF3 and CF3 CH2CHCF3 + CF3CH2 CHCF3
✍ Derek R. McDowell; Bert E. Holmes πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 412 KB πŸ‘ 2 views

Disproportionationkombination rate constant ratios, kd/&[, for the reactive collision between CF3CH2CHX + CF, radicals and between CF3CH2CHX + CF3CH2CHX radicals have been measured for X = CF, The kd/k, = 0.066 -t 0 01 3 when H is transferred to the CF3 radical and 0 I25 ? 0.025 for H transfer to th

Substituent effects on the disproportion
Substituent effects on the disproportionationβ€”combination rate constant ratios for gas-phase halocarbon radicals, Part 5: Reactions of CF3 + CF3CH2CHCH3 and CF3CH2CHCH3 + CF3CH2CHCH3
✍ John D. Ferguson; Bert E. Holmes πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 184 KB

## Abstract Rate constant ratios, __k__~d~/__k__~c~ for the disproportionation/combination reaction have been measured as 0.07 Β± 0.02 when an H is removed from the CH~2~ position of the CF~3~CH~2~CHCH~3~ radical and as 0.24 Β± 0.03 when the H is removed from the CH~3~ position in the reaction with t