K r a m e r s 1) has derived a diffusion equation in phase space, describing the motion of a particle subject to an external force and to the shuttling action of the Brownian forces caused by a surrounding medium in temperature equilibrium. In this paper a solution of Kramers' equation is obtained
The group theory of molecular diffusion and chemical reactions in the liquid state of matter
β Scribed by M.W. Evans
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 517 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0167-7322
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
We calculate the effective reaction rate constant k\* and the effective diffusion constant D\* for a system of independently distributed overlapping sinks as functions of the volume fraction ~b of the sinks and the Sherwood number Sh. The Sherwood number characterises the strength of the reaction on
H. A. Kr a m e r s 1) has studied the rate of chemical reactions in view of the Brownian forces caused by a surrounding medium in temperature equilibrium. In a previous paper 3) the author gave a solution of Kramers' diffusion equation in phase space by systematic development. In this paper the gene