The ground state of a tetragonally compressed copper(II) complex
โ Scribed by Adam J. Bridgeman; Malcolm A. Halcrow; Marcus Jones; Elmars Krausz; Nayan K. Solanki
- Book ID
- 108313088
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 156 KB
- Volume
- 314
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Replacing the 3- and 3''-protons of the ligand 2,6-di(pyrazol-1-yl)pyridine L by mesityl groups changes the electronic ground state of [Cu(L) ] complexes from {dโxโ2-yโ2} to {dโzโ2} . This is the best example so far for a "homoleptic" Jahn-Teller-compressed six-coordinate Cu complex.
In the problem of the "compressed helium atom", the boundary condition that the wave function ~0 must vanish at infinity (1" : oo), is replaced by : ~ = 0 at a finite r = r o. This problem is solved by a variational method, which for the limiting case of the free atom.(ro--+ oo) coincideswith one of