The geometry and efficacy of cation–π interactions in a diagonal position of a designed β-hairpin
✍ Scribed by Chad D. Tatko; Marcey L. Waters
- Book ID
- 111752196
- Publisher
- Cold Spring Harbor Laboratory Press
- Year
- 2009
- Tongue
- English
- Weight
- 205 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0961-8368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The effects of N‐methylation and chain length on a cation–π interaction have been investigated within the context of a β‐hairpin peptide. Significant enhancement of the interaction and structural stabilization of the hairpin have been observed upon Lys methylation. Thermodynamic analysi
## Abstract Designed octapeptides Boc‐Leu‐Val‐Val‐Aib‐^D^Xxx‐Leu‐Val‐Val‐OMe (^D^Xxx = ^D^Ala, 3a;^D^Val, 3c and ^D^Pro, 5a) and Boc‐Leu‐Phe‐Val‐Aib‐^D^Ala‐Leu‐Phe‐Val‐OMe (3b) have been investigated to construct models of a stable type I′ β‐turn nucleated hairpin and to generate systems for invest