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The generality of the nitroso-glyoxylate reaction: Conversion ofp-nitronitrosobenzene to the hydroxamic acid

✍ Scribed by M. D. Corbett; B. R. Corbett


Book ID
105411682
Publisher
Springer
Year
1982
Tongue
English
Weight
209 KB
Volume
38
Category
Article
ISSN
1420-682X

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Iridium(I)-catalyzed hydrogen peroxide o
✍ Seiji Iwasa; Ahmad Fakhruddin; Yasuyuki Tsukamoto; Masayuki Kameyama; Hisao Nish πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 68 KB

## Ir(I)(coe) 2 Cl] 2 (2 mol%)-catalyzed hydrogen peroxide oxidation of hydroxamic acids in the presence of cyclopentadiene gave the corresponding cycloadducts up to 97% yield. With a catalyst loading of 0.05 mol%, a maximum TON was attained to 740.