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The General Equation of Supercritical Gas Adsorption Isotherm

✍ Scribed by Murata, Katsuyuki; Kaneko, Katsumi

Book ID
125985579
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
96 KB
Volume
105
Category
Article
ISSN
0022-3654

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Based on a modified form of the Gibbs equation, two conditions of thermodynamical correctness have been defined. According to these conditions the change in the free energy of the surface-calculable from all isotherm equations-must have finite limiting values at \(\theta \rightarrow 0\) and \(\theta