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The Gaseous Oxidation of Tertiary Aliphatic Amines. I. Triethylamine

โœ Scribed by Cullis, C. F.; Waddington, D. J.


Book ID
120144816
Publisher
The Royal Society
Year
1958
Tongue
English
Weight
979 KB
Volume
244
Category
Article
ISSN
0962-8444

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The dealkylation of tertiary aliphatic a
โœ David S. Millan; Rolf H. Prager ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 174 KB

Phenyl chlorothionoformate reacts rapidly with aliphatic amines at 20ยฐC to give a thiourethane and an alkyl chloride. The urethanes are readily converted to the secondary amine salt by reaction with dimethyl sulfate, followed by hydrolysis with water. Rates of reaction, and alkyl group cleavage sele