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The Gaseous Oxidation of 2-Methyl-but-2-ene. I. Kinetic and Analytical Studies

✍ Scribed by Cullis, C. F.; Fish, A.; Turner, D. W.

Book ID
120145423
Publisher
The Royal Society
Year
1961
Tongue
English
Weight
458 KB
Volume
262
Category
Article
ISSN
0962-8444

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✍ John O. Morley; A. Jayne Oliver Kapur; Michael H. Charlton 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 265 KB

## Abstract The kinetics of the ring‐opening reactions of the 3‐isothiazolones (**1a–d**) with aqueous 2‐methyl‐2‐propanethiol has been explored at pH 4. The results strongly suggest that the reaction is second order in thiol and third order overall. Extrapolation of the kinetic data gives third‐or