The acidity of aliphatic alcohols in gas phase is reinvestigated with the aim at establishing the simplest, yet reliable, level of description to be used for the solute in a solution-phase acidity calculation. It is shown that a procedure which includes only the differential correlation effects aris
β¦ LIBER β¦
The fragmentation of proton-bound cluster ions and the gas-phase acidities of alcohols
β Scribed by Michael J. Haas; Alex G. Harrison
- Book ID
- 107920575
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 828 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0168-1176
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The rearrangement of the molecular ions of the isomeric 2-and fmethyl benzofurans (1 and 2), 2H-chromene (3) and 4H-chromene (4) has been studied as a further example of the isomerization of oxygen-heteroaromatic radical cations via a ring expansionlring contraction mechanism well documented for mol