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The fragmentation behaviour of alkylated thiophene-1,1-dioxides

โœ Scribed by H. Budzikiewicz; U. Gerhard


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
246 KB
Volume
24
Category
Article
ISSN
1076-5174

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Fragmentation behaviour of alkylated thi
โœ H. Budzikiewicz; D. Lange ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 354 KB

It is shown that thiophene-1,l-dioxides carrying an alkyl chain in the 2-and +positions can be readily distinguished by the characteristic fragmentation mode of the latter, viz. benzylic cleavage of the side-chain with back-transfer of two hydrogen atoms (I M --CnHIn-, 1 '). By deuterium labelling i