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The Formation of Thiachroman as a Major Product in the Claisen Rearrangement of Allyl Phenyl Sulfide 1

✍ Scribed by Meyers, Cal Y.; Rinaldi, Costantino; Bonoli, Luciano


Book ID
120578413
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
424 KB
Volume
28
Category
Article
ISSN
0022-3263

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Ketene Formation or Phenyl-Group Migrati
✍ Evangelos G. Bakalbassis; Spyros Spyroudis; Constantinos A. Tsipis πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 439 KB

## Abstract Phenyliodonium ylides of hydroxyquinones easily undergo intramolecular rearrangements associated with phenyl‐group migration or ketene formation under ambient conditions. The mechanism of the two rival potential reaction paths was explored by electronic structure calculation techniques