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The formation of tetracyclo[7.2.1.02,5.02,8]dodeca-6,10-dienes under conditions of thermal isomerization of spiro[2.4]hepta-4,6-diene into bicyclo[3.2.0]hepta-1,3-diene

✍ Scribed by Yu. V. Tomilov; A. B. Kostitsyn; E. V. Shulishov; O. M. Nefedov


Book ID
112387607
Publisher
Springer
Year
1993
Tongue
English
Weight
554 KB
Volume
42
Category
Article
ISSN
1573-9171

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✍ Dehmlow, Eckehard V. ;Bollmann, Christof πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 332 KB

Title compound 1 is sterically shielded to such an extent that many "normal" reactions cannot occur. It is possible, however, to prepare the carboxylic acid 2, its acyl chloride 3 and the oxidation product 4. Furthermore, halogen substitutions to yield 5 and 6 and trialkylstannations to give 8a, b c