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The formation of light emitting cerium silicates in cerium-doped silicon oxides

✍ Scribed by Li, Jing; Zalloum, Othman; Roschuk, Tyler; Heng, Chenglin; Wojcik, Jacek; Mascher, Peter


Book ID
119955450
Publisher
American Institute of Physics
Year
2009
Tongue
English
Weight
617 KB
Volume
94
Category
Article
ISSN
0003-6951

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Carbon silicon bond cleavage in the oxid
✍ Enrico Baciocchi; Tiziana Del Giacco; Cesare Rol; Giovanni Vittorio Sebastiani πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 234 KB

Benzyltrirrethylsilanes react with cerium(IV) ammonium nitrate in AcOH to give products -of C-Si cleavage (benzyl nitrate and acetate), under very mild conditions and in quantitative yields. The reaction rate is very sensitive to the nature of the ring substituents (y= -5.4), which clearly suggests