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The Formation of Ketones by a Reaction Equivalent to R-+R′COCH2+→R′COCH2R

✍ Scribed by Katritzky, AR; Wrobel, L; Savage, GP; Deyrupdrewniak, M

Book ID
115533318
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1990
Tongue
English
Weight
294 KB
Volume
43
Category
Article
ISSN
0004-9425

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Application of the iron acyl complex R-(-)-[(η5-C5H5)Fe(CO)(PPh3)- COCH2O({{1R,2S}},5Rmenthyl)] as a homochiral formyl anion equivalent
✍ Stephen G. Davies; David Middlemiss; Alan Naylor; Martin Wills 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 307 KB

## Surnmnry: The enantiomerically pure iron acyl complex R-(-)-[($-CSH5)Fe(CO)(PPh3)-CUCH20({lR,2S,5R]menthyl))] tepresents a source of homochiral formyl anion equivalent applicable to the synthesis of enantiomerkally pare a-hydroxy acetals from aldehydes. The formyl anion or a synthetic equivale