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The Formation of Hypoiodous Acid and Hydrated Iodine Cation by the Hydrolysis of Iodine

โœ Scribed by Allen, T. L.; Keefer, R. M.

Book ID
127110683
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
458 KB
Volume
77
Category
Article
ISSN
0002-7863

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The kinetics of the gas-phase thermal iodination of hydrogen sulfide by 12 to yield HSI and HI has been investigated in the temperature range 555-595 K. The reaction was found to proceed through an I atom and radical chain mechanism. Analysis of the kinetic data yields log k (l/mol-sec) = (11.1 f 0.