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The formation of dinucsear μ-hydroxo-cobalt(III) complexes

✍ Scribed by G. Schwarzenbach; J. Boesch; H. Egli

Book ID
118908747
Publisher
Elsevier Science
Year
1971
Weight
822 KB
Volume
33
Category
Article
ISSN
0022-1902

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Reactions of oxygenated cobalt (II) comp
Reactions of oxygenated cobalt (II) complexes. XIII. Diastereoisomeric forms of μ-peroxo-μ-hydroxo-bis[bis(ethylenediamine) cobalt(III)]. Preparation, X-ray structure determination and reactivity
✍ Silvio Fallab; Margareta Zehnder; Ulf Thewalt 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 German ⚖ 413 KB

## Abstract Oxygenation of solutions containing bis(ethylenediamine) cobalt(II) ions leads to a mixture of diastereomeric forms of μ‐peroxo‐μ‐hydroxo‐bis[bis(ethylenediamine) cobalt(III)] cations. The existence of a meso‐isomer has now been proved by its isolation as perchlorate and by an X‐ray str