The formation of diacetyl and acetoin from α-acetolactic acid
✍ Scribed by J. C. de Man
- Book ID
- 104586061
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 286 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0165-0513
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✦ Synopsis
Abstract
Of several ions tested, only Fe^+3^, Cu^+2^ and Al^+3^ catalysed the decarboxylation of α‐acetolactic acid at pH 4.8.
At pH 2.2, only Fe^+3^ and Cu^+2^ were active.
Fe^+3^ and Cu^+2^ were shown to form complexes with α‐acetolactic acid.
Fe^+3^ and Cu^+2^ not only decarboxylated but also oxidized α‐acetolactic acid, with, as a result, formation of diacetyl.
Decarboxylation of α‐acetolactic acid by these ions is compatible with the mechanism suggested by Martell and Calvin.
α‐Acetolactic acid is subject to autoxidation. 2‐Butene‐2,3‐diol may be an intermediate product.
📜 SIMILAR VOLUMES
## Abstract Nine strains of starter cultures belonging to the genera __Streptococcus, Leuconostoc and Lactobacillus__ were studied for the effect of pyruvate concentration, incubation period and the associative growth on the production of acetoin and diacetyl in skim milk. The absolute amount of ac