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The Formation of 7-Oxabicyclo[4.2.0]octanes and 6-Oxabicyclo[3.2.1]octanes via Cationic Iodocyclization.

โœ Scribed by Christopher J. Nichols


Publisher
John Wiley and Sons
Year
2003
Weight
77 KB
Volume
34
Category
Article
ISSN
0931-7597

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The geometry and the n-electronic structure of 6,7-dimethyl-3-oxabicyclo[3.2.O]hepta-l,4,6triene (4) is analyzed by M N D O calculations and by the interpretation of the He-I-photoelectron spectrum. The calculated bond length alternations in 4 indicate olefinic resp. antiaromatic character. As H O M