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The formation and reactivity of dimolybdenum acetylide anions; synthesis, structure, and thermal rearrangement of dimolybdenum ?1,?2-(4e)-vinylidene complexes

✍ Scribed by Mercer, Richard J.; Green, Michael; Orpen, A. Guy


Book ID
120077347
Publisher
The Royal Society of Chemistry
Year
1986
Tongue
English
Weight
362 KB
Volume
7
Category
Article
ISSN
0022-4936

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## Abstract 4,4‐Dichloro‐1,1‐diphenyl‐2‐azabuta‐1,3‐diene (1) oxidatively adds to [Pd(PPh~3~)~4~] and [Pt(C~2~H~4~)(PPh~3~)~2~] giving rise to the σ‐alkenyl complexes __trans__‐[MCl{[C(Cl)=C(H)−N=CPh~2~]}(PPh~3~)~2~] (2a: M = Pd; 2b: M = Pt). When 1 is treated with [Pd(PPh~3~)~4~] in a 1:2 ratio in