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THE FORMATION AND DECAY OF H 2 O 3 AND HO 2 IN ELECTRON-IRRADIATED AQUEOUS SOLUTIONS 1

โœ Scribed by Czapski, Gideon; Bielski, Benon H. J.

Book ID
121486809
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
587 KB
Volume
67
Category
Article
ISSN
0022-3654

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The Dependence on H2O and on NH3 of the
The Dependence on H2O and on NH3 of the Kinetics of the self-reaction of HO2 in the gas-phase formation of HO2ยทH2O and HO2ยทNH3 complexes
โœ Edwin J. Hamilton Jr.; Ruey-Rong Lii ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 538 KB

Electron pulse radiolysis a t -298'K of 2 atm Hz containing 5 torr 0 2 produces HOz free radical whose disappearance by reaction (I), HOz + HOz -HzOz + 0 2 , is monitored by kinetic spectrophotometry a t 230.5 nm. Using a literature value for the HOz absorption cross section, the values k = 2.5 X cm