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The fluorescence of polybenzyl

✍ Scribed by Bryan Ellis; P.G. White; R.N. Young

Publisher: Elsevier Science
Year: 1969
Tongue: English
Weight: 432 KB
Volume: 5
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(69)90067-6

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✦ Synopsis

Polybenzyl, prepared by treating benzyl chloride with stamk chloride in the presence of air at room temperature, is fluorescent. The fluorescence and absorption spectra of this polybenzyl have been determined. From these spectral studies together with the reactions of polybenzyl with butyl lithium and sodium/potassium alloy, it has been established that the most probable fluorescent unit is a benzyl substituted 9 phenyl or 9:lO diphenyl anthracene. A possible mechanism is given for the formation of this fluorescent group via the formation of a carbonium ion of diphenyl methane type.

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