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The Flash Photolysis of 1,3,5-Cycloheptatriene and Some 7-Substituted Derivatives

✍ Scribed by B. A. Thrush; J. J. Zwolenik


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
406 KB
Volume
71
Category
Article
ISSN
0037-9646

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1,3,5-Cycloheptatriene (1) and various 7-alkyl-1,3,5-cycloheptatrienes (3, 6, 9, 13, and 16-19) were subjected to gas-phase protonation under and conditions and the MIKE spectra of their [ M + H ] ' ions CI(CH 4 ) CI(iC 4 H 10 ) were measured. Loss of from the parent ion [ 1 + H ] ' and almost exclu

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-2-oxopropyl]triphenylarsonium bromide 8 with 7-methoxy-3,7-dimethyloctanal 10 in the presence of a base gave bis(1-methylethyl) 4,7-dihydroxy-2-(6-methoxy-2,6-dimethylheptyl)-3,5,7-cycloheptatriene-1,3-dicarboxylate 7b. The formation of 7b can be explained by a number of consecutive steps. The mech