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The First Trimetallic Pd/Tl/Co Carbonyl Cluster, Trigonal [Pd9{μ3-TlCo(CO)3L}(μ2-CO)6(μ3-CO)3L6]: Ligand-Stabilization of the Trigonal-Bipyramidal [TlCo(CO)3L] Entity

✍ Scribed by Evgueni G. Mednikov; Charles G. Fry; Lawrence F. Dahl

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
193 KB
Volume
117
Category
Article
ISSN
0044-8249

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Intramolecular Site Exchange of Carbonyl
Intramolecular Site Exchange of Carbonyl Ligands in the Cluster Compounds Nonacarbonyl{μ3-[η3-(1,3,5-trithiane)]}triruthenium ([Ru3(CO)9{μ3-(η3-C3H6S3)}]) and (tert-Butyl Isocyanide)octacarbonyl-{μ3-[η3-(1,3,5-trithiane)]}triruthenium ([Ru3(t-BuNC)(CO)8{μ3-(η3-C3H6S3)}])
✍ Gábor Laurenczy; Andrée. Merbach; Bertrand Moullet; Raymond Roulet; Lisa Hoferka 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 German ⚖ 293 KB

## 211. Intramolecular Site Exchange of Carbonyl Ligands in the Cluster Compounds Nonacarbonyl{p,-[q3-( 1,3,5-trithiane)])triruthenium ([ Ru,(C O),{,u ,-(q 3-C3H,S3)} I) and (tevt-But yl1socyanide)octacarbonyl-{p3-[q3-( 1,3,5-trithiane)]) triruthenium ([Ru,(t-BuNC)(CO),{p,-(q3-C,~S,)}])