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The first total synthesis of veiutamine, a new type of pyrroloiminoquinone marine alkaloid

โœ Scribed by Yoshihiro Moro-oka; Tsutomu Fukuda; Masatomo Iwao

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
229 KB
Volume
40
Category
Article
ISSN
0040-4039

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New synthetic approach to pyrroloiminoqu
New synthetic approach to pyrroloiminoquinone marine alkaloids. Total synthesis of makaluvamines A, D, I, and K
โœ Masatomo Iwao; Osamu Motoi; Tsutomu Fukuda; Fumito Ishibashi ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 740 KB

A new entry into pyrroloiminoquinone marine alkaloids, makaluvamines, has been developed. The key 1,3,4,5-tetrahydropyrrolo[4,3,2-de]quinoline intermediates 11 and 18 were laepared by atyne-mediated cyclization of the 4-chloro-6-methoxytryptamine derivatives 10 and 17, respectively. The requisite s